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. 2019 Apr 10;24(7):1404. doi: 10.3390/molecules24071404

Table 5.

Mass flow of fermentation volatiles present in samples collected during RO-EP treatment of Trial 2 wines.

Wine D Wine E P
Wine in Wine out Retentate Permeate Pre-EP Permeate Post-EP Strip Water Wine in Wine out Retentate Permeate Pre-EP Permeate Post-EP Strip Water
straight chain acids acetic acid 1 2.15 2.00 1.48 0.57 0.53 0.34 1.73 1.63 1.32 0.40 0.31 0.16 <0.001
propanoic acid 6.94 6.93 4.63 3.44 2.69 1.62 4.82 4.71 4.13 0.94 0.66 0.62 0.001
butanoic acid 3.62 2.18 2.83 0.64 <0.22 <0.28 2.83 2.69 2.45 0.55 <0.21 <0.39 <0.001
hexanoic acid 6.65 6.36 5.47 1.49 0.88 0.83 4.78 4.53 4.17 0.71 <0.21 <0.39 <0.001
octanoic acid 7.77 6.98 5.54 0.97 0.46 0.53 4.01 3.62 3.50 0.55 <0.21 0.56 0.013
decanoic acid 1.62 1.58 1.24 0.24 <0.09 0.18 1.85 1.69 1.53 0.29 0.17 0.44 <0.001
straight chain ethyl esters ethyl acetate 1 0.39 0.30 0.30 0.09 0.02 0.05 0.23 0.19 0.19 0.04 <0.01 0.04 0.004
ethyl propanoate 1.49 1.08 1.20 0.33 0.05 0.19 0.78 0.64 0.67 0.14 <0.02 0.12 0.008
ethyl butanoate 0.97 0.73 0.79 0.17 0.03 0.10 0.64 0.53 0.57 0.08 <0.01 0.07 <0.001
ethyl hexanoate 1.42 1.06 1.21 0.21 0.04 0.14 0.10 0.09 0.09 0.01 <0.01 0.01 0.377
ethyl octanoate 0.94 0.68 0.79 0.13 0.03 0.07 0.11 0.08 0.10 0.02 <0.01 0.02 0.319
ethyl decanoate 0.51 0.32 0.39 0.04 0.01 0.02 0.02 0.01 0.02 <0.01 <0.01 <0.01 0.467
branched acids 2-methylpropanoic acid 5.33 4.84 4.15 1.03 0.64 0.58 5.92 5.63 5.49 0.67 0.27 0.41 <0.001
2-methylbutanoic acid 45.86 38.99 41.58 5.50 2.13 1.94 4.51 4.28 4.25 0.31 0.15 0.29 0.329
3-methylbutanoic acid 5.19 4.77 4.71 0.74 0.39 0.32 5.05 4.80 4.57 0.34 0.15 0.27 <0.001
branched ethyl esters ethyl 2-methylpropanoate 1.06 0.94 1.02 0.11 0.03 0.06 0.47 0.37 0.44 0.04 <0.01 0.03 0.033
ethyl 2-methylbutanoate 0.16 0.13 0.15 0.01 <0.01 <0.01 0.09 0.08 0.10 0.01 <0.01 0.01 0.006
ethyl 3-methylbutanoate 0.26 0.21 0.24 0.02 <0.01 0.01 0.14 0.12 0.14 0.01 <0.01 0.01 0.009
acetates 2-methylpropyl acetate 0.16 0.13 0.15 0.02 <0.01 0.01 0.17 0.15 0.16 0.01 <0.01 <0.01 <0.001
2-methylbutyl acetate 0.60 0.48 0.54 0.06 0.01 0.06 0.40 0.36 0.39 0.02 <0.01 0.02 <0.001
3-methylbutyl acetate 1.86 1.45 1.64 0.19 0.04 0.21 3.94 3.50 3.79 0.25 0.02 0.26 0.034
hexyl acetate 0.03 0.01 0.02 0.00 <0.01 0.01 0.08 0.06 0.06 0.01 <0.01 0.01 0.141
2-phenylethyl acetate 0.93 0.73 0.79 0.16 0.03 0.13 3.21 2.95 2.93 0.30 0.03 0.30 0.140
alcohols 2-methylpropanol 1 0.21 0.19 0.19 0.03 0.01 0.02 0.25 0.23 0.23 0.02 <0.01 0.02 <0.001
butanol 5.62 4.85 4.21 1.38 0.56 1.13 5.83 5.35 5.08 0.92 0.26 0.94 <0.001
2/3-methylbutanol 1 0.48 0.44 0.42 0.06 0.01 0.04 1.24 1.24 1.25 0.15 0.01 0.12 0.064
1-hexanol 7.01 5.97 5.82 1.19 0.22 0.87 13.70 12.17 11.90 1.77 <0.04 1.71 0.018
2-phenylethanol 1 0.90 0.86 0.72 0.16 0.11 0.05 1.55 1.50 1.33 0.22 0.13 0.10 0.008

1 Concentrations are g/h, except for acetic acid, ethyl acetate, 2-methylpropanol, 2-methylbutanol and 2-phenylethyl ethanol, which are kg/h < denotes below limit of detection.