Table 1.

Combined electrochemical/photochemical iodide-mediated process for C–H amination.^[a]

Entry	Potential/V vs Fc/Fc+	TBAI	Yield/%
1	0.3	10 mol%	4%
2	0.4	10 mol%	70%
3	0.5	10 mol%	75% (72%)
4	0.5	-	n.d.
5[b]	0.5	10 mol%	19%

^[a]The reaction was performed on a 0.5 mmol scale under constant potential (CP) conditions, yields were determined by ¹H NMR with m-xylene as an internal standard; isolated yield shown in parenthesis.

^[b]Without irradiation.

TFE = 2,2,2-Trifluoroethanol. n.d. = not detected.