Table 1. Formal reduction potentials a .
Species | DA+/0 | RuCP22+/+ | RuCP22+*/+ | Re(i) |
Couple | +˙/0 | 2+/+ | 2+*/+ | 1+/0˙ |
E′ (V) | 0.71 | –1.20 | 0.90 | –1.19 |
aOn nanoITO electrodes, V vs. NHE at room temperature in acetonitrile 0.1 M in LiClO4 measured using a Ag+/Ag quasi-reference electrode referenced internally to the ferrocenium/ferrocene couple with Fc+/Fc taken as 0.62 V vs. NHE.