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Understanding solvent effects on aryl CH···anion receptors is the next frontier in understanding the nature of this unique bond. Triazolophane macrocycles 22a and 22b showed a predictable 1/εr dependency in aprotic solvents but an unexpected linear decrease in anion association strength in protic solvents. Graphs reproduced with permission of Elsevier from ref. 52. Copyright 2017.
