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. 2019 Mar 14;58(17):5697–5701. doi: 10.1002/anie.201814452

Table 2.

Allylation reaction substrate scope.[a]

graphic file with name ANIE-58-5697-g006.jpg

[a] General conditions: Pyridinium (1.0 equiv), allyl sulfone (3.0 equiv), and 5 (1.5 equiv) in DMA (0.4 m) at 40 °C for 16 h. Yields are of isolated products after flash column chromatography. [b] Isolated after acetyl protection of the alcohol. [c] Reactions performed at 60 °C with 5 (2.5 equiv) and Et3N (3.0 equiv).