Skip to main content
. 2019 Mar 25;10(17):4542–4549. doi: 10.1039/c9sc00135b

Table 1. Comparison of the properties and stabilities of the parent MOFs and their corresponding MOF-composites soaked under highly acidic or basic conditions for 24 hours. Ticks mean stable and crosses mean unstable.

Sample name/formula BET surface area (m2 g–1) Contact angle (°) Polymer loading (wt%) H2SO4 treatment, pH = 0, 1, 2 or 3 for 24 h BET surface area after H2SO4 treatment (m2 g–1) NaOH treatment, pH = 11, 12 or 13 for 24 h BET surface area after NaOH treatment (m2 g–1)
HKUST-1 Cu3(BTC)2, BTC3– = benzene-1,3,5-tricarboxylate 1843 ∼0 × ×
HKUST-1@PDA-SF 1286 140 16.2 1247 1242
HKUST-1@PDA-SF-2 1600 135 6.8 1586 1571
ZIF-67 Co(MIm)2, MIm = 2-methylimidazolate 1466 67 × ×
ZIF-67@PDA-SF 683 147 16.8 729 738
ZIF-67@PDA-SF-2 1312 139 11.5 1303 1293
ZIF-8 Zn(MIm)2, MIm = 2-methylimidazolate 1788 ∼0 × 1710
ZIF-8@PDA-SF 1389 149 7.6 1387 1411
Mg-MOF-74 Mg2(dobdc), dobdc4– = 2,5-dioxido-1,4-benzenedicarboxylate 1182 ∼0 × 1138
Mg-MOF-74@PDA-SF 918 138 12.8 867 952
MIL-100-Fe Fe3(BTC)2, BTC3– = benzene-1,3,5-tricarboxylate 1587 ∼0 × 1579
MIL-100-Fe@PDA-SF 1266 127 14.7 1369 1262
UiO-66 Zr6O4(OH)4(BDC)6, BDC2– = 1,4-dicarboxybenzene 1430 ∼0 × ×
UiO-66@PDA-SF 638 141 10.3 626 581
Cu-TDPAT Cu3(TDPAT), TDPAT = 2,4,6-tris(3,5 dicarboxylic phenylamino)-1,3,5-triazine 2254 ∼0 × ×
Cu-TDPAT@PDA-SF 1835 146 12.5 1784 1778