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Hydroacylation Scope with Styrenyl Olefins[a]
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With 0.10 mmol of 3.
With 0.10 mmol of 3. Isolated yields are given. Diastereoselectivities were determined by 1H NMR analysis of the unpurified reaction mixture. Enantioselectivities (ee’s) were determined by chiral SFC analysis. (RP)-1-[(S)-tert-Butylphosphinoyl]-2-[(S)-1-(diphenylphosphino)ethyl]ferrocene (L4) is abbreviated as JoSPOphos.
