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Comparison of Ligand Exchange Reactions in the Presence and Absence of Ascorbate
| Compound | t1/2 (h) No Ascorbate | t1/2 (h) With Ascorbate | % C at t1/2 No Ascorbate | % C at t1/2 With Ascorbate |
|---|---|---|---|---|
| [Co(3F-salen)(NH3)2]+ | 29.8 ± 0.3 | 16.8 ± 0.1 | 4 | 30 |
| [Co(3F-salen)(3F-BnNH2)2]+ | 2.62 ± 0.14 | 2.6 ± 0.1 | 9 | 28 |
| [Co(tfacen)(NH3)2]+ | 48.6 ± 0.2 | 35.8 ± 2.6 | 4 | 34 |
| [Co(tfacen)(3F-BnNH2)2]+ | 11.2 ± 0.1 | 11.7 ± 0.6 | 2 | 26 |
