Skip to main content
. 2019 Apr 8;10(18):4727–4741. doi: 10.1039/c9sc01351b

Table 2. Group 14 element containing radicals and the distribution of spin density.

Compounds Spin density Type of radical Ref.
23 Not given Monoradical 21
24 40% CcAAC, 28% O, 24% NcAAC, 6% C Monoradical 22a
25 Not given Disbiradical 22a
26a 42% CcAAC, 28% O Monoradical 22b
26b 39% CcAAC, 29% O Monoradical 22b
26c 37% CcAAC, 31% O Monoradical 22b
26d 31% CcAAC, 33% O Monoradical 22b
27 19% CcAAC, 36% O Monoradical 22b
28 Not given Dis-triradical 22a
29 Not given Triplet 22c
30 Not given Triplet 22c
31 41.1% CcAAC, 21.1% NcAAC, 25% (C4F4N) Monoradical 22d
32 33% CcAAC, 23% NcAAC, 10% CNHC Monoradical cation 22e
33 25% CcAAC, 20% NcAAC, 9% CNHC Monoradical cation 22e
34 Not given Monoradical cation 23
35a 60% on C4 unit, 40% NcAAC Monoradical cation 24
35b 44% NcAAC, 24% CcAAC, 31% CcAAC Monoradical cation 25
36c 43% CcAAC, 15% NcAAC, 39% CtBu, 2.5% Cment Monoradical 26b
36d 45% CcAAC, 17% NcAAC, 38% CCPh3 Monoradical 26b
37a Not given Biradicaloid 26c
37b–c Not given Disbiradical 26c
38a 58% cAAC, 38% linker Monoradical cation 26d
38b 50% cAAC, 50% linker Monoradical cation 26d
38c 52% cAAC, 48% linker Monoradical cation 26d
39 (37–45%) Ccarbene, (8–11%) Ncarbene, (19–23%) Cortho, (19–29%) Cpara Monoradical 26e
40 Not given Biradicaloid 26f and g
41 Not given Disbiradical 27
42 Not given Disbiradical and OSS 28
43 90% CcAAC, 10% NcAAC Disbiradical 29
44 65% CcAAC, 18% NcAAC OSS 30
45a–b 71% CcAAC, 22% NcAAC, 6% Si Monoradical 31
45c 66% CcAAC, 25% NcAAC Monoradical 30
46 80% CcAAC, 16% NcAAC, 5% Si Monoradical 32
47 Not given CSS biradicaloid 33
48 Not given Monoradical anion 35
49 Not given OSS 36
50 95% CcAAC, 5% NcAAC Disbiradical 29
51 92% CcAAC, 8% NcAAC Disbiradical 29
52 52% Si Monoradical cation 37