Fructose |
UHPLC-C-CAD |
Solvent: CH3CN |
0.1261 |
0.0452 |
0.998 |
01–30.0 |
N/A |
Matrix (raw fermented cocoa) |
-0.0006 |
0.0424 |
0.998 |
0.2–30.0 |
Low level: 117.0 |
Intermediate level: 112.2 |
High level: 108.4 |
Matrix (dry cocoa) |
0.0138 |
0.0431 |
0.996 |
0.4–30.0 |
Low level: 113.9 |
Intermediate level: 111.8 |
High level: 117.7 |
Glucose |
UHPLC-C-CAD |
Solvent: CH3CN |
0.0964 |
0.0389 |
0.999 |
0.1–30.0 |
N/A |
Matrix (raw fermented cocoa) |
0.015 |
0.0424 |
0.997 |
0.5–30 |
Low level: 87.3 |
Intermediate level: 77.8 |
High level: 103.4 |
Matrix (dry cocoa) |
0.0101 |
0.0432 |
0.997 |
0.6–30 |
Low level: 104.0 |
Intermediate level: 79.6 |
High level: 95.6 |
Sucrose |
UHPLC-C-CAD |
Solvent: CH3CN |
0.1516 |
0.0534 |
0.998 |
0.1–30.0 |
N/A |
Matrix (raw fermented cocoa) |
0.0111 |
0.0457 |
0.998 |
0.4–30.0 |
Low level: 120.2 |
Intermediate level: 110.2 |
High level: 116.4 |
Matrix (dry cocoa) |
0.0288 |
0.0437 |
0.997 |
0.4–30.0 |
Low level: 84.8 |
Intermediate level: 111.2 |
High level: 111.1 |
Maltose |
UHPLC-C-CAD |
Solvent: CH3CN |
0.0444 |
0.0373 |
0.999 |
0.1–50 |
N/A |
Matrix (raw fermented cocoa) |
0.0188 |
0.0314 |
0.996 |
5.0–50.0 |
Low level: 112.8 |
Intermediate level: 102.0 |
High level: 118.1 |
Matrix (dry cocoa) |
-0.0396 |
0.0347 |
0.998 |
5.0–50.0 |
Low level: 113.2 |
Intermediate level: 91.0 |
High level: 119.7 |
Mannitol |
UHPLC-C-CAD |
Solvent: CH3CN |
0.0888 |
0.0515 |
0.999 |
0.1–30.0 |
N/A |
Matrix (raw fermented cocoa) |
-0.0161 |
0.0473 |
1.000 |
0.4–30 |
Low level: 106.4 |
Intermediate level: 84.7 |
High level: 90.6 |
Matrix (dry cocoa) |
-0.0146 |
0.0491 |
0.998 |
0.3–30 |
Low level: 110.9 |
Intermediate level: 104.6 |
High level: 110.0 |
Phenylalanine |
UHPLC-C-CAD |
Matrix (well-fermented and dry cocoa) |
-1.0253 |
0.0761 |
0.999 |
1.0–60 |
68 |
Leucine |
0.1257 |
0.0627 |
0.998 |
1.0–60 |
96.2 |
Methionine |
-0.2386 |
0.1547 |
0.996 |
1.0–60 |
<70 |
Valine |
|
|
-0.7939 |
0.1069 |
0.998 |
1.0–60 |
75.2 |
Cysteine |
0.1923 |
0.0631 |
0.998 |
1.0–60 |
116.3 |
Asparagine |
-0.0707 |
0.077 |
0.999 |
1.0–60 |
114.6 |
Lysine |
-0.4354 |
0.1158 |
0.999 |
1.0–60 |
79.9 |
Citric |
0.105 |
0.0382 |
0.996 |
0.1–70 |
117.9 |
Malic |
0.0897 |
0.0428 |
0.997 |
0.1–70 |
79.2 |
Oxalic |
-0.015 |
0.0405 |
0.995 |
0.1–70 |
>120 |
Succinic |
0.0462 |
0.0121 |
0.999 |
0.1–70 |
|
Acetic acid |
HPLC-DAD |
Matrix (well-fermented and dry cocoa) |
-0.0034 |
0.0161 |
0.992 |
3.0–20.0 |
85 |
GC-MS |
Matrix (well-fermented and dry cocoa) |
215916.7125 |
1341.7457 |
0.999 |
0.5–100 |
72 |
Lactic acid |
HPLC-DAD |
Matrix (well-fermented and dry cocoa) |
-0.0253 |
0.0145 |
0.995 |
3.0–20.0 |
86 |
Theobromine |
UHPLC-TQD/ESI |
Matrix (well-fermented and dry cocoa) |
425.072 |
1945.29 |
0.999 |
2.5–100 |
103.87 |
Caffeine |
-2541.82 |
13804.2 |
0.999 |
0.02–50 |
106.27 |
Theophylline |
-970.582 |
10170.6 |
0.999 |
0.02–50 |
>120 |
Epicathequine |
-468.281 |
1546.46 |
1.000 |
0.02–50 |
|
Cathequine |
-209.54 |
198.18 |
0.995 |
0.02–50 |
|
Total polyphenols |
Spectrofluorometer |
Solvent |
-0.0044 |
0.0037 |
0.999 |
10–100 |
N/A |
ORAC |
Spectrofluorometer |
Solvent |
2.8258 |
0.0838 |
0.994 |
10–600 |
N/A |