Table 3.
Some Relevant Electronic Absorption Spectral Data [גmax in nm] for [MoO2{ON=C(CH3)Ar}2] and
[MoO2{OC(R)CHC(R’)=NC6H5}2].
| S. No. | Complex | n→π* | π →π* | Ot→MoVI |
|---|---|---|---|---|
| 1 | [MoO2{ON=C(CH3)C4H3S}2] | 365 (1.59) | 210 (0.39) | 318 (1.67) |
| 2 | [MoO2{ON=C(CH3)C4H3O}2] | 353 (1.66) | 218 (0.77) | 325 (1.56) |
| 3 | [MoO2{ON=C(CH3)C5H4N}2] | 375 (1.57) | 213 (0.91) | 315 (1.13) |
| 4 | [MoO2{OC(CH3)CHC(CH3)=NC6H5}2] | 369 (1.37) | 217 (-0.60) | 319 (1.01) |
| 5 | [MoO2{OC(CH3)CHC(C6H5)=NC6H5}2] | 370 (1.33) | 215 (-0.69) | 315 (0.63) |
| 6 | [MoO2{OC(C6H5)CHC(C6H5)=NC6H5}2] | 371 (1.32) | 216 (-0.68) | 309 (0.63) |