Table 2.
Experimental gas-phase rate coefficients for the OH+CH3OH reaction obtained in this work together with those from previous studies at T=100-200 K. Uncertainties ±σ reported here for this work are only statistical.
ca. T./ K | T/ K | Bath Gas |
n / 1016 molecule cm-3 |
k(T)/ 10-11 cm3molecule-1 s-1 |
Reference |
---|---|---|---|---|---|
~ 100 | 99.3 ± 0.4 | N2 | 7.67 ± 0.09 | 4.76 ± 0.05 | This work |
101.8 ± 0.6 | Ar | 18.34 ± 0.17 | 3.74 ± 0.08 | This work | |
~ 107 | 107.0 ± 0.5 | N2 | 4.90 ± 0.06 | 2.03 ± 0.02 | This work |
106.0 ± 0.6 | Ar | 14.02 ± 0.11 | 2.15 ± 0.07 | This work | |
115.3 ± 1.1 | Ar | 9.58 ± 0.14 | 1.85 ± 0.07 | This work | |
~ 123 | 123 ± 5* | He | 3.15 ± 0.15 | 0.43 ± 0.21 | Gómez-Martín et al.13 |
122.5 ± 1.0 | Ar | 7.20 ± 0.08 | 1.21 ± 0.04 | This work | |
130 ± 5* | He | 6.6 ± 0.3 | 0.39 ± 0.21 | Gómez-Martín et al.13 | |
~ 137 | 138 ± 9 | N2 | 7.8 ± 1.0 | 0.53 ± 0.17 | Gómez-Martín et al.13 |
136.1 ± 0.8 | N2 | 24.92 ± 0.35 | 1.83 ± 0.08 | This work | |
140.4 ± 1.0 | N2 | 21.68 ± 0.40 | 1.24 ± 0.03 | This work | |
~ 143 | 143 ± 5* | He | 2.76 ± 0.14 | 0.31 ± 0.12 | Gómez-Martín et al.13 |
143.3 ± 0.6 | N2 | 17.02 ± 0.17 | 1.36 ± 0.03 | This work | |
~150 | 153.1 ± 0.7 | N2 | 9.14 ± 0.11 | 0.98 ± 0.04 | This work |
149.9 ± 0.7 | N2 | 10.69 ± 0.12 | 1.28 ± 0.10 | This work | |
148.3 ± 0.6 | N2 | 12.35 ± 0.13 | 1.84 ± 0.04 | This work | |
158.8 ± 0.6 | N2 | 7.40 ± 0.07 | 0.43 ± 0.02 | This work | |
~ 165 | 163 ± 5* | He | 2.46 ± 0.13 | 0.17 ± 0.07 | Gómez-Martín et al.13 |
165.7 ± 0.9 | N2 | 5.64 ± 0.08 | 0.17 ± 0.01 | This work | |
177.5 ± 1.2 | N2 | 6.71 ± 0.11 | 0.071 ± 0.003 | This work | |
180 ± 10* | He | 1.59 ± 0.08 | 0.07 ± 0.02 | Gómez-Martín et al.13 | |
202 ± 2* | He | 1.30 ± 0.06 | 0.060 ± 0.008 | Gómez-Martín et al.13 |
Flow tube technique