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. 2019 Apr 18;10(20):5283–5289. doi: 10.1039/c9sc00501c

Table 2. Au-catalyzed reactions of 1e–s a .

Inline graphic
1 R1 Ar Time (h) 2 Yield b (%)
1 1e p-MeOC6H4 Ph 8 2e 92
2 1f p-ClC6H4 Ph 8 2f 94
3 1g p-F3CC6H4 Ph 20 2g 86
4 1h 1-Cyclohexenyl Ph 8 2h 51
5 1i Cy Ph 12 2i 81
6 1j iPr Ph 15 2j 53
7 1k 1-Phenylpentyl Ph 8 2k 61
8 1l nPr Ph 24 <1
9 1m tBu Ph 6 <1 c
10 1n H Ph 24 <1 d
11 1o Ph p-MeOC6H4 8 2o 65
12 1p Ph p-ClC6H4 8 2p 92
13 1q Ph p-F3CC6H4 8 2q 91
14 1r 4-MeOC6H4 p-F3CC6H4 12 2r 93
15 1s Ph 1-Naphthyl 8 2s 93

aReaction of 1 (0.2 mmol) were conducted in the presence of PPh3AuNTf2 (0.01 mmol) in DCE (0.4 mL) at 50 °C.

bIsolated yield.

c76% of 1m was recovered.

d28% of 1n was recovered.