Table 2. Au-catalyzed reactions of 1e–s a .
| ||||||
| 1 | R1 | Ar | Time (h) | 2 | Yield b (%) | |
| 1 | 1e | p-MeOC6H4 | Ph | 8 | 2e | 92 |
| 2 | 1f | p-ClC6H4 | Ph | 8 | 2f | 94 |
| 3 | 1g | p-F3CC6H4 | Ph | 20 | 2g | 86 |
| 4 | 1h | 1-Cyclohexenyl | Ph | 8 | 2h | 51 |
| 5 | 1i | Cy | Ph | 12 | 2i | 81 |
| 6 | 1j | iPr | Ph | 15 | 2j | 53 |
| 7 | 1k | 1-Phenylpentyl | Ph | 8 | 2k | 61 |
| 8 | 1l | nPr | Ph | 24 | — | <1 |
| 9 | 1m | tBu | Ph | 6 | — | <1 c |
| 10 | 1n | H | Ph | 24 | — | <1 d |
| 11 | 1o | Ph | p-MeOC6H4 | 8 | 2o | 65 |
| 12 | 1p | Ph | p-ClC6H4 | 8 | 2p | 92 |
| 13 | 1q | Ph | p-F3CC6H4 | 8 | 2q | 91 |
| 14 | 1r | 4-MeOC6H4 | p-F3CC6H4 | 12 | 2r | 93 |
| 15 | 1s | Ph | 1-Naphthyl | 8 | 2s | 93 |
aReaction of 1 (0.2 mmol) were conducted in the presence of PPh3AuNTf2 (0.01 mmol) in DCE (0.4 mL) at 50 °C.
bIsolated yield.
c76% of 1m was recovered.
d28% of 1n was recovered.