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. Author manuscript; available in PMC: 2020 May 29.
Published in final edited form as: J Am Chem Soc. 2019 May 16;141(21):8557–8573. doi: 10.1021/jacs.9b02443

Figure 3.

Figure 3

Kinetic Tests for Catalyst Deactivation and Product Inhibition for Reactions Run in Neat Substrate (A–C) or Toluene Solution (D–F). (A./D.) Concentration of substrate [5b] over time measured by gas chromatographic analysis of aliquots removed from the reaction mixture. (B./E.) Concentration of substrate [5b] over time time-shifted to illustrate overlay with standard conditions. (C./F.) Reaction rate over the course of substrate consumption shown over evenly spaced intervals of Δ[5b] = 0.25 M. Open markers represent data points obtained from individual trials; closed markers represent average values obtained from duplicate trials. [Fe]tot = [(MePI)Fe(MviMvi)]0 = 2.5 mM for all trials. See Supporting Information for additional experimental details.