Table 2.
Absorption (λabs,max) and emission (λem,max) maxima of the ICAAc derivatives at pH = 3 and pH = 11, respectively, in aqueous buffer.
Compound | pH = 3 | pH = 11 | I3/I11 | pKa | pKa | ||
---|---|---|---|---|---|---|---|
λabs,max | λem,max | λabs,max | λem,max | ||||
(nm) | (nm) | (UV-vis) | (PL) | ||||
ICAAc | 470 | 554 | 428 | 553 | 2.25 | 7.05 ± 0.02 | 6.96 ± 0.07 |
monoMICAAc | 475 | 553 | 446 | 553 | 1.61 | 7.35 ± 0.07 | 7.22 ± 0.15 |
diMICAAc | 502 | 577 | 470 | 572 | 0.58 | 7.58 ± 0.03 | 7.71 ± 0.13 |
I3/I11 is the fluorescence intensity ratio measured at pH = 3 and pH = 11. pKa is the acid dissociation constant at a logarithmic scale.