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. Author manuscript; available in PMC: 2020 Jun 12.
Published in final edited form as: J Am Chem Soc. 2019 May 28;141(23):9106–9123. doi: 10.1021/jacs.9b03337

Scheme 11.

Scheme 11.

Oxidative addition of (a) H2 and a C(sp)─H bond to (iPrPNP)CoCH3 to yield the corresponding cobalt(III) products (reference 87), and (b) the C(sp2)─D bond of C6D6 affording a Co(I) phenyl complex (reference 87).