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. Author manuscript; available in PMC: 2020 Jun 12.
Published in final edited form as: J Am Chem Soc. 2019 May 28;141(23):9106–9123. doi: 10.1021/jacs.9b03337

Scheme 14.

Scheme 14.

Reaction of (iPrPNP)CoCH2SiMe3 with (a) the equimolar amount of B2Pin2 and subsequent addition of CO (reference 101) and (b) excess B2Pin2 and subsequent oxidative addition of HBPin (reference 101).