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. Author manuscript; available in PMC: 2020 Jun 12.
Published in final edited form as: J Am Chem Soc. 2019 May 28;141(23):9106–9123. doi: 10.1021/jacs.9b03337

Scheme 23.

Scheme 23.

(a) Borylation of 3-fluorobenzotrifluoride by the in-situ activated (SiNSi)CoBr2 precatalyst. Conditions: THF, 100°C, 24 h (reference 110) and (b) selected substrate scope for the borylation catalyzed by (SiNSi)CoBr2 (reference 115). Reported % numbers are isolated yields.