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. Author manuscript; available in PMC: 2020 Jun 12.
Published in final edited form as: J Am Chem Soc. 2019 May 28;141(23):9106–9123. doi: 10.1021/jacs.9b03337

Scheme 5.

Scheme 5.

(a) Net 2-electron oxidative addition of an allyl ether over two iron centers to yield a mixture of an iron ethoxide and an iron allyl complex (reference 45). (b) C─O bond cleavage by oxidative addition of vinyl acetate on iron(0) (reference 45).