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. Author manuscript; available in PMC: 2020 Jun 12.
Published in final edited form as: J Am Chem Soc. 2019 May 28;141(23):9106–9123. doi: 10.1021/jacs.9b03337

Scheme 6.

Scheme 6.

(a) Reaction of (iPrPDI)Fe(N2)2 with H2 (top) and PhSiH3 (bottom) (reference 35a). (b) Synthesis of (iPrPNP)FeH2(N2) (reference 52). (c) Oxidative addition of a Si-H bond of PhSiH3 by (iPrPNP)FeH2(N2) (reference 52).