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Examples of post-synthetic modification of frameworks to improve the electronic conductivity. (a) [Fe2(BDP)3]n where BDP represents 1,4-benzenedipyrazolate, where chemical reduction improves the conductivity and (b) the introduction of new pathways for electronic delocalization (blue) in the framework [Cu3(BTC)2]n by intercalation with TCNQ guests. Reproduced with permission from Macmillan Publishers Limited [40,78].
