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. Author manuscript; available in PMC: 2020 Feb 20.
Published in final edited form as: J Am Chem Soc. 2019 Feb 11;141(7):3083–3099. doi: 10.1021/jacs.8b12247

Figure 3.

Figure 3.

(A) Overarching synthetic strategy to convert cedrol (15) to the Illicium sesquiterpenes. (B) Known enzymatic (left) and chemical (right) methods for the oxidation of 15. (C) Precedented ring shift to convert the cedrane skeleton to the allo-cedrane one.