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. 2019 Apr 26;10(21):5461–5469. doi: 10.1039/c9sc00912d

Table 2. The d-band center and the DOS integral differences of the surface (S) and active site (AS) for each model. The active site for Mo(100) is the hcp site of Mo4; the active sites for Tc(0001), Ru(0001), MoRu(0001)-1 are the fcc/hcp sites of Tc3, Ru3, and Ru3; the active sites for MoRu(0001)-2, MoRu(0001)-3, and MoRu(0001)-4 are the fcc/hcp sites of Mo2Ru.

S/AS d-band center (eV) Integral differences
Tc(0001) S(AS) –1.40 0
Ru(0001) S(AS) –1.90 5.49
Mo(100) S(AS) –0.99 4.75
MoRu(0001)-1 S(AS) –1.70 3.06
MoRu(0001)-2 S –1.32 2.99
MoRu(0001)-2 AS –1.39 2.83
MoRu(0001)-3 S –1.29 2.45
MoRu(0001)-3 AS –1.38 2.38
MoRu(0001)-4 S –1.47 2.99
MoRu(0001)-4 AS –1.39 2.99