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. 2019 May 14;12(10):1576. doi: 10.3390/ma12101576
A Parameter of the damage rate function ωf
b Length of a chain Kuhn’s segment
ca, cmax Actual and maximum number of active chain per unit volume, respectively
D Damage parameter of the material
D Dissipated energy per unit volume of material
Dv,Df Dissipated energy per unit volume of material related to the viscous and to the chain’s failure mechanisms, respectively
F,Fij Deformation gradient tensor
t Time
J Polymer volume change ratio
ka,kd Activation and deactivation cross-link rates of the polymer chains, respectively
kB Boltzmann’s constant
L, Lij Spatial velocity gradient
L, L1 Langevin function and its inverse, respectively
N Number of segments in a polymer chain belonging to a single network
q(N) Probability distribution function of the number of Kuhn’s segments in a polydisperse polymer
r End-to-end vector of a polymer chain
f Force in a single stretched chain
T Absolute temperature
wb Strain energy of a single Kuhn segment
w¯ Bond energy between two segments of a polymer chain
γ Parameter of the damage rate function ωf
φ0(r),φ(r) Distribution function of the end-to-end vector in the stress-free and in the current state, respectively
λ Unidimensional stretch measure
ωf(r) Failure rate related to the chains with end-to-end vector r
ρ(r) Chain Configuration Density Function (CCDF)
ρ˙, ρ˙L, ρ˙v, ρ˙f Total CCDF rate, CCDF rate due to deformation, viscous effects and failure, respectively
ψ Deformation energy for a single chain
Ψ0,Ψ Network’s deformation energy per unit volume in the stress-free and in the current configuration, respectively
σ Chauchy stress