|
A
c
|
Upstream interception area |
|
A(s) |
Function of far-field approaching |
|
B
|
Width of deformed droplets |
|
a, b
|
Adjustable dimensionless parameters of Equation (34) |
|
ac, am
|
Parameters of Equation (64) |
|
C(i, j): |
Coagulation kernel—Equation (1) |
|
C
|
Ratio of circulation length and droplet distance—Equation (33) |
|
Ca
|
Capillary number Equation (2) |
|
Cac
|
critical c.n. |
|
C
H
|
Parameter of coalescence in a blend—Equation (62) |
|
D
|
Droplet deformation—Equation (7) |
|
D* |
Dimensionless function in Equation (37) |
|
E
|
Rate of strain tensor |
|
E
DK
|
Volume energy—Equation (58) |
|
F(i) |
Overall breakup frequency—Equation (1) |
|
F
|
Drag force |
|
F
c
|
Driving force of the coalescence—Equation (29); FS in shear flow; Fe in uniaxial extension |
| f |
General functions—Figure 3; not the same in Equation (23); another fF in Equation (61) |
|
h
|
Distance between droplets surfaces |
|
h
c
|
critical distance |
|
G’ |
Storage modulus |
|
G’m
|
s.m. of matrix |
|
G’d
|
s.m. of the dispersed phase |
| g(m) |
Function defined by Equation (31) |
|
g(p) |
function defined by Equation (66) |
|
I
|
Unit second-order tensor |
|
J
|
Rate of coalescence |
|
J
0
|
r.c. without interdroplet interactions |
| K(p, Λ) |
Function in Equations (36) and (37) |
|
k
i
|
Parameters in Equations (15b) and (64) |
|
L
|
Length of deformed droplets |
|
m
|
Parameter defined by Equation (32) |
|
m
|
Orientation vectors |
|
n
|
Number of droplets |
|
ni, nj
|
of radius Ri, Rj
|
|
n
k
|
of volume V1—Equation (1) |
|
n
|
Number of spherical droplets in a volume unit—Equation (57) |
|
n
f
|
Number of fragments/daughter droplets |
|
nf(i) |
formed at breakup of a droplet of volume iV1
|
|
n
|
Outward unit normal to the spherical contact surface |
|
N1,d, N1,m
|
The first-normal stress differences of the droplets and matrix |
|
P
c
|
Collision efficiency |
|
p
|
Ratio of disperged phase and matrix viscosity ηd/ηm
|
|
q
|
The growth rate |
|
R
|
Droplet radius |
|
R
c
|
critical d.r. for breakup |
|
R* = R/Rc
|
reduced d.r. |
|
R
0
|
r. of parent droplet |
|
R
f
|
r. of formed droplets |
|
R
d
|
r. of daughter droplets |
|
R
eq
|
equivalent d.r. def. by Equation (35) |
|
R
L
|
r. of steep decrease in Pc
|
|
R
F
|
parameter of Equation (51) |
|
r
|
The vector from the center of droplet 1 to the center of droplet 2 |
|
r
0
|
Initial thread radius |
|
r
f
|
Radius of flattened part of a droplet—Equation (29) |
|
S
|
Surface |
|
s
|
Dimensionless center-to-center distance s = r/R
|
|
t
|
Time |
|
t
B
|
Breakup t. |
|
t
s
|
Local minimum of Equation (20) |
|
t
g
|
t. needed for the growth of α to its critical value |
|
t
c
|
t. of coalescence |
|
t
i
|
interaction t. |
|
tB* |
Dimensionless breakup time |
|
u
|
Velocity of a particle |
|
v
|
Velocity |
|
v12(r) |
relative velocity of colliding droplets |
|
V
1
|
Elementary volume |
|
x, y, z
|
Spatial Cartesian coordinates |
|
x
|
2πR/λ —Equation (20) |
|
x
m
|
Dominant wave number Equation (23) |
|
α(t) |
Distortion amplitude at time t
|
|
α
0
|
initial d.a. |
|
β
|
Parameter in Equations (44)–(46) |
|
|
Shear rate |
|
eff
|
effective s.r. |
|
|
Stretching rate |
|
ζ
|
Friction resistance |
|
η
|
Viscosity |
|
η
m
|
matrix v. |
|
η
d
|
droplets/dispersed phase v. |
|
η
ap
|
apparent v. of the blend |
|
θ
|
Polar angle |
| Λ |
Ratio of radii of smaller to larger droplet |
|
λ
|
Wavelength of droplet breakup |
|
λ
m
|
dominant w.; λ0 at t = 0 |
|
λ
r
|
Ratio of the magnitude of the strain rate tensor to the sum of magnitudes of the strain rate and vorticity tensors |
| μ |
Parameter of Equation (66) |
|
σ
|
Interfacial tension |
|
σ
ef
|
effective if.t. |
|
τ
m
|
Relaxation time |
|
,
|
Functions in Equation (20) defined in [7] |
|
φ
|
Azimuth |
|
ϕ
|
Volume fraction of the dispersed phase |
| Ψ (λ, p) |
Function in Equation (17) |
| Ω |
Angular velocity tensor |
| ω(i, j) |
Probability that a fragment formed by the breakup of a droplet of volume jV1 will have volume iV1
|
| EPR |
Ethylene-propylene rubber |
| PCL |
Poly(caprolactone) |
| PLA |
Poly(lactic acid) |
| PP |
Polypropylene |