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. 2019 Jun 13;7:397. doi: 10.3389/fchem.2019.00397

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Copyright © 2019 Nichols and Machan.

This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.

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(A) Co(Cp)(P₂N₂) utilizing pendent tertiary amines for reduction of CO₂ to formate. (B) Fe(^tbudhbpy)CI is protonated at the Fe-coordinating O atoms upon reduction and reduces CO₂ to formate. (C) Macrocyclic–aminopyridyl complex which reduces CO₂ to CO.