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. 2019 May 23;10(22):5851–5852. doi: 10.1039/c9sc90095k

Table 2. Copolymerization reaction conditions a .

Cat. Catalyst (mol%) Temp. (°C) Pressure (bar) PCHC b (%) TON b TOF b (h–1) M n [Đ] b
2b 0.1 120 1 >96 377 435 12 280 [1.04]
5340 [1.13]
2c 0.1 120 1 >93 419 466 14 490 [1.06]
5930 [1.15]
2e 0.1 120 1 >99 430 645 21 760 [1.04]
9090 [1.15]
2c 0.01 120 20 >99 4415 8830 44 400 [1.04]
21 200 [1.05]
2c 0.005 120 20 >99 5435 1359 54 380 [1.04]
26 550 [1.04]

aReactions were carried out in a Parr high pressure vessel with an impeller at 20 bar.

bSee Table 1 and ESI for all data (Fig. S56–S60).