Table 2. Copolymerization reaction conditions a .
Cat. | Catalyst (mol%) | Temp. (°C) | Pressure (bar) | PCHC b (%) | TON b | TOF b (h–1) | M n [Đ] b |
2b | 0.1 | 120 | 1 | >96 | 377 | 435 | 12 280 [1.04] |
5340 [1.13] | |||||||
2c | 0.1 | 120 | 1 | >93 | 419 | 466 | 14 490 [1.06] |
5930 [1.15] | |||||||
2e | 0.1 | 120 | 1 | >99 | 430 | 645 | 21 760 [1.04] |
9090 [1.15] | |||||||
2c | 0.01 | 120 | 20 | >99 | 4415 | 8830 | 44 400 [1.04] |
21 200 [1.05] | |||||||
2c | 0.005 | 120 | 20 | >99 | 5435 | 1359 | 54 380 [1.04] |
26 550 [1.04] |
aReactions were carried out in a Parr high pressure vessel with an impeller at 20 bar.
bSee Table 1 and ESI for all data (Fig. S56–S60).