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. 2018 Dec 15;27(1):9–20. doi: 10.1007/s40199-018-0232-2

Table 2.

Parameters and values of Langmuir, Freundlich, Temkin and Dubinin-Radushkevich models and free energy for the adsorption of CUR

Model Equation Isotherm constant CUR
Langmuir Ceqe=Ceqm+1kqm (6) qm (mg/g) 2.0 × 103
k (L/mg) 0.017
R 2 0.997
Freundlich log qe =  log  KF + (1/n) log  Ce (7) KF [(mg/g)/(mg/g)1/n] 75.85
1/n 1.88
R 2 0.945
Temkin qe = BlnA + BlnCe (8) A (L/mg) 0.025
B (kJ/mol) 371
R 2 0.979
Dubinin-Radushkevich

ln qe =  ln  qs − Kad(ε2) (9)

ε = RT  ln (1 + 1/Ce) (9.1)

qs (mg/g) 910
kad (mol2/kJ) −3.704
R 2 0.557
Free energy E=1/2Kad (10) E (kJ/mol) 0.367