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. 2019 Feb 11;58(12):3957–3961. doi: 10.1002/anie.201814577

Table 3.

Cyclopropanation by 5 ae from 1 ae (left) or through decarbenation of 4 a (right).[a] Inline graphic

Entry Precursor Yield [%][b]
3 c 3 d 3 e
1 1 a 99 80 99 (2.3:1)
2 1 b 87 90 99 (3:1)
3 1 c 99 99 99 (1:1.2)
4 1 d 99 (1:1.5)31 99 72 (1:2.1)
5 1 e 99 90 99 (3.5:1)
6 4 a 32 38 17 (1:7.5)

[a] Yields determined by 1H NMR spectroscopy using Ph2CH2 as the internal standard. [b] Diastereomeric ratio given within parenthesis. DCE=1,2‐dichloroethane.