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Molecular structure of 3 (thermal ellipsoids at 50 % probability; H atoms omitted for clarity). Selected bond lengths [Å] and angles [°]: Bi1−C1: 2.199(2); Bi1−C23: 2.278(2); N1−C1: 1.334(3); N1−C11: 1.452(2); N1−C4: 1.516(3); C1−C2: 1.519(3); N1‐C1‐Bi1: 119.65(14); C1‐Bi1‐C23: 99.60(8); C1‐N1‐C11:120.45(17); C1‐N1‐C4: 115.43(16); C11‐N1‐C4: 124.08(16); N1‐C1‐C2: 109.53(17).17
