Diamond magnetic microscopy. (a) NV energy-level diagram depicting
magnetic sublevels (|0〉, 1), optical (green arrow), fluorescence (red
arrows), and nonradiative (gray arrows) pathways. Gray arrows excitation show
spin-selective intersystem crossing leading to polarization into the |0〉
ground-state sublevel. (b) Energy splitting of the ground-state sublevels in an
external magnetic field applied along the NV axis. Blue arrows indicate the
f± microwave transitions. (c) Example of
an ODMR spectrum. From the separation between peaks, the projection of the local
magnetic field along the NV axis is inferred. (d) Epifluorescence ODMR
microscope used for magnetic imaging. Dry hemozoin crystals are placed on top of
a diamond substrate with an ~ 0.2-μm top layer
doped with NV centers. (e) Experimental and photoelectron-shot-noise-limited
detection threshold for 65 × 65 nm2 detection pixels versus
averaging time. The experimental data are fit to the function
with α = 8.4 ± 0.1 μT
s1/2