Table 2.
1H and13C chemical shifts for CM1 and CMS.
| Sugar residues | H1/C1 | H2/C2 | H3/C3 | H4/C4 | H5/C5 | H6/C6 | OCH3 |
|---|---|---|---|---|---|---|---|
| A (CM1) | 5.15 | 4.06 | 3.90 | 3.74 | 3.74 | 4.18,4.23 | |
| α-D-Manp(1→ | 102.10 | 70.91 | 71.91 | 68.51 | 74.04 | 59.42 | |
| B (CM1) | 5.06 | 4.05 | 3.88 | 3.69 | 3.74 | 4.18,4.23 | |
| →2)α-D-Manp(1→ | 100.68 | 78.38 | 70.24 | 68.51 | 74.04 | 59.42 | |
| C (CM1) | 5.01 | 4.02 | 4.05 | 3.79 | 3.69 | 3.54,3.58 | |
| β-D-Galf(1→ | 106.25 | 81.12 | 76.28 | 81.79 | 72.54 | 62.33 | |
| D (CM1) | 4.99 | 4.05 | 4.10 | 3.90 | 3.73 | 3.53,3.58 | |
| →2)β-D-Galf(1→ | 106.25 | 87.04 | 76.10 | 81.79 | 70.24 | 62.83 | |
| E (CM1) | 4.78 | 3.94 | 3.89 | 3.84 | 3.79 | 3.68,4.04 | 3.08 |
| →2,6)α-D-Manp(1→ | 99.30 | 78.38 | 70.91 | 68.51 | 70.56 | 65.96 | 54.10 |
| F (CM1) | 4.29 | 3.41 | 3.56 | 3.78 | 3.70 | 4.10,3.93 | |
| →4)β-D-Glcp(1→ | 103.34 | 72.54 | 75.21 | 81.12 | 75.20 | 61.11 | |
| A (CMS) | 4.88 | 3.45 | / | / | / | 3.70,3.62 | |
| α-D-Glcp(1→ | 98.12 | 71.25 | 72.3 | 68.56 | 72.81 | 63.22 | |
| B (CMS) | 4.78 | 3.30 | 3.38 | 3.54 | 3.74 | 3.96,3.72 | |
| →6)β-D-Glcp | 94.06 | 73.76 | 76.28 | 70.67 | 74.86 | 69.13 | |
| C (CMS) | 4.38 | 3.19 | 3.36 | 3.48 | 3.62 | 4.07,3.78 | |
| →6)β-D-Glcp(1→ | 103.28 | 73.62 | 75.87 | 70.24 | 75.18 | 69.13 |