Table 1.
Photocatalysta | Yield (%)b | TON (based on CsPbBr3)c | ||||||||
---|---|---|---|---|---|---|---|---|---|---|
1a | 1c | 1d | 2a | 3f | 1a | 1c | 1d | 2a | 3f | |
CsPbBr3 P1 | 84 | 85 | 76 | 84 | 70 | 9,100 | 830 | 280 | 380 | 33 |
Ru(bpy)3(PF6)2 | Trace | 60 | 25 | Trace | N.R. | – | 60 | 25 | – | – |
Ir(ppy)3 | 79 | N.R. | N.R. | 63 | 65 | 79 | – | – | 63 | 33 |
CdSe QDs (525 nm) | Trace | Trace | N.R. | N.R. | N.R. | – | – | – | – | – |
abpy 2,2′-bipyridine, ppy ortho-metalated 2-phenylpyridine
baverage yield using for P1
cdetails in Supplementary Note 2