A,B. ΔV1/2 as a function of
concentration of iso-propyl (A) and
tert-butyl (B) phenols and cyclohexanols. Data
are reproduced from Figure 3. Solid blue
lines are simultaneous fits of the common site model (S=4) to the data in these
two panels and to the data in panels C-E.
C-E. ΔV1/2 as a function of
concentration of DIP-CH (C), DTB-CH (D) or DIP-P
(E), in the presence of 3 μM DTB-P. The solid blue lines
are as defined in panels A and B. The dashed blue
lines are the predicted behavior of the distinct site model at S=4 using the
association constants determined from the fit of the common site model. The
green lines report the mean value of ΔV1/2 (solid) and SEM
(dashed) elicited by 3 μM DTB-P in paired controls for each additivity
condition. The number of independent determinations in C,
D and E were 27, 80 and 33, respectively.
E. Association constants determined from the fits of the
common site model with S=4 (as per
A-E and reported in Table 4) transformed to free energy terms according to equation 6. The reported value of
the opening equilibrium constant (L) is from this same fit.