Table 3.
Chemical shits of ‘slow’ diastereomer, ppm.
| dT | dC | d(p*A) | |
|---|---|---|---|
| H1' | 6.23 | 6.09 | 6.44 |
| H2 | – | – | 8.19 |
| H2' | 2.27 | 2.02 | 2.88 |
| H2'' | 2.42 | 2.42 | 2.63 |
| H3' | 4.73 | 4.92 | 4.75 |
| H4' | 4.11 | 4.20 | 4.26 |
| H5 | – | 5.96 | – |
| H5' & H5'' | 3.74 и 3.79 | 3.98 и 3.99 | 4.17 и 4.22 |
| H6 | 7.41 | 7.64 | – |
| H7 | 1.82 | – | – |
| H8 | – | – | 8.33 |
| C1' | 88.14 | 88.42 | 86.25 |
| C2 | 160.69 | 159.89 | 155.52 |
| C2' | 40.22 | 40.7 | 41.27 |
| C3' | 78.11 | 78.64 | 73.20 |
| C4 | 177.5 | 168.65 | 151.56 |
| C4' | 88.02 | 86.40 | 87.82 |
| C5 | 114.45 | 99.1 | 121.40 |
| C5' | 63.94 | 68.10 | 67.29 |
| C6 | 139.29 | 143.84 | 158.2 |
| C7 | 15.37 | – | – |
| C8 | – | – | 142.40 |
| (CH3)2–N–CN-Cp*A | 2.87 | ||
| (CH3)2–N–CN–C*pA | 42.42 | ||
| -C N-Cp*A | 165.91 | ||
| TpC | −0.89 | ||
| Cp*A | 0.21 | ||