Table 2.
Catalyst | Conversion (%) | Selectivity (%) | Benzaldehyde yield (%) | TOF (h−1) | |
---|---|---|---|---|---|
Benzaldehyde | Benzyl benzoate | ||||
1Pd/OMC−750 | 15.81 | 87.14 | 9.73 | 13.78 | 5022 |
1Pd/NOMC−0.3–750 | 24.63 | 85.71 | 13.56 | 21.11 | 8696 |
1Pd/NOMC−0.6–750 | 23.52 | 86.39 | 12.62 | 20.32 | 7901 |
1Pd/NOMC−0.9–750 | 20.13 | 86.05 | 12.44 | 17.32 | 6804 |
Reaction conditions: catalyst, 20 mg; benzyl alcohol, 50 mmol; O2, 20 mL/min; temperature, 160°C; reaction time, 3h.