Table 3.
Catalytic properties of Pd-containing catalysts supported on NOMC-0.3–750a.
| Entry | Catalyst | Temperature (°C) | Conversion (%) | Selectivity (%) | TOF (h−1) | |
|---|---|---|---|---|---|---|
| Benzaldehyde | Benzyl benzoate | |||||
| 1 | 1Pd/NOMC−0.3–750 | 70 | 1.19 | 96.12 | 2.93 | 420 |
| 2 | 1Pd/NOMC−0.3–750 | 100 | 5.27 | 94.76 | 4.89 | 1,861 |
| 3 | 1Pd/NOMC−0.3–750 | 130 | 13.41 | 92.51 | 6.68 | 4,734 |
| 4 | 1Pd/NOMC−0.3–750 | 160 | 24.63 | 85.71 | 13.56 | 8,698 |
| 5 | 0.5Pd/NOMC−0.3–750 | 160 | 22.78 | 86.10 | 12.62 | 8,041 |
| 6 | 2Pd/NOMC−0.3–750 | 160 | 16.5 | 84.79 | 13.95 | 6,495 |
a
Reaction conditions: benzyl alcohol/Pd = 250 mol/g; O2, 20 mL/min−1; temperature, 160 °C; reaction time, 3h.