Table 1.
No. | Components | RT | Formula | CAS | Score | RI | Contents * (%) |
---|---|---|---|---|---|---|---|
1 | 5-Methyl-5-hexen-2-ol | 2.07 | C7H14O | 50551-88-7 | 70.73 | 692 | 3.65 |
2 | 2-Ethyl-furan | 2.14 | C6H8O | 3208-16-0 | 77.37 | 708 | 1.41 |
3 | 1-(Methylencyclopropyl)-ethanol | 2.36 | C6H10O | 70.89 | 725 | 0.14 | |
4 | 4-Penten-1-ol | 2.69 | C5H10O | 821-09-0 | 65.28 | 766 | 0.43 |
5 | 2, 4-Dimethyl-3-pentanol | 3.10 | C7H16O | 600-36-2 | 80.18 | 803 | 3.75 |
6 | 3-Furaldehyde | 3.72 | C5H4O2 | 498-60-2 | 90.06 | 829 | 4.73 |
7 | (E)-2-hexenal | 4.15 | C6H10O | 6728-26-3 | 80.70 | 849 | 1.07 |
8 | 4-Methyl-2-penten-1-ol | 4.46 | C6H12O | 5362-55-0 | 67.13 | 863 | 0.59 |
9 | Heptanal | 5.42 | C7H14O | 111-71-7 | 67.55 | 904 | 0.27 |
10 | (+/-)-2-Amino-1-propanol | 5.61 | C3H9NO | 2749-11-3 | 72.19 | 910 | 0.13 |
11 | 1-(2-Furanyl)-ethanone, | 5.83 | C6H6O2 | 1192-62-7 | 60.92 | 916 | 0.30 |
12 | Butyrolactone | 6.26 | C4H6O2 | 96-48-0 | 63.77 | 923 | 0.21 |
13 | (1R)-2, 6, 6-Trimethylbicyclo [3.1.1] hept-2-ene | 6.50 | C10H16 | 7785-70-8 | 54.28 | 936 | 0.14 |
14 | 1-Methyl-3-cyclohexen-1-ol | 7.27 | C7H12O | 33061-16-4 | 53.39 | 959 | 0.12 |
15 | Benzaldehyde | 7.36 | C7H8O | 100-52-7 | 87.31 | 962 | 1.52 |
16 | 1-Methyl-pyrazole-4-carboxaldehyde | 7.53 | C5H6N2O | 25016-11-9 | 73.89 | 966 | 0.41 |
17 | 2-Methyl-1-hepten-6-one | 8.34 | C8H14O | 10408-15-8 | 69.68 | 991 | 0.19 |
18 | 2-Pentyl-furan | 8.46 | C9H14O | 3777-69-3 | 77.14 | 994 | 0.57 |
19 | 1-Methyl-1H-pyrrole-2-carboxaldehyde | 8.90 | C6H7NO | 1192-58-1 | 67.63 | 1004 | 0.31 |
20 | Benzeneacetaldehyde | 10.22 | C8H8O | 122-78-1 | 85.65 | 1023 | 0.81 |
21 | 2, 5-Furandicarboxaldehyde | 11.44 | C6H4O3 | 823-82-5 | 61.79 | 1042 | 0.19 |
22 | Nonanal | 12.27 | C9H18O | 124-19-6 | 74.41 | 1107 | 0.20 |
23 | Levomenthol | 12.38 | C10H20O | 2216-51-5 | 65.21 | 1110 | 0.16 |
24 | Phenylethyl alcohol | 12.57 | C8H10O | 60-12-8 | 73.38 | 1116 | 0.17 |
25 | 2, 6, 6-Trimethyl-1, 3-cyclohexadiene-1-carboxaldehyde | 15.27 | C10H14O | 116-26-7 | 61.78 | 1202 | 0.10 |
26 | 2, 6, 6-Trimethyl-1-cyclohexene-1-carboxaldehyde | 15.90 | C10H16O | 432-25-7 | 64.44 | 1204 | 0.16 |
27 | 4-(2, 6, 6-Trimethyl-1, 3-cyclohexadien-1-yl)-2-butanone | 17.11 | C13H20O | 20483-36-7 | 66.03 | 1266 | 0.20 |
28 | (1R, 2R, 5R, E)-7-Ethylidene-1, 2, 8, 8-tetramethylbicyclo [3.3.1] octane | 17.61 | C14H14 | 193695-14-6 | 54.09 | 1283 | 0.17 |
29 | Tetrahydro-6-propyl-2H-pyran-2-one | 17.79 | C8H14O2 | 542-28-9 | 69.71 | 1289 | 0.19 |
30 | 2, 6, 10, 10-Tetramethyl-1-oxaspiro [4.5] dec-6-ene | 18.17 | C13H22O | 36431-72-8 | 80.79 | 1302 | 0.25 |
31 | (3R-trans)-4-Ethenyl-4-methyl-3-(1-methylethenyl)-1-(1-methylethyl)-cyclohexene | 19.24 | C15H24 | 20307-84-0 | 73.27 | 1342 | 0.14 |
32 | trans-Calamenene | 19.57 | C15H22 | 73209-42-4 | 74.69 | 1355 | 0.14 |
33 | α-Cubebene | 20.28 | C15H24 | 17699-14-8 | 81.24 | 1381 | 0.17 |
34 | β-Elemene | 20.52 | C15H24 | 515-13-9 | 97.06 | 1389 | 0.63 |
35 | 2, 4, 6-Trimethyl-decane | 20.85 | C12H26 | 2801-84-5 | 51.23 | 1402 | 0.11 |
36 | δ-Selinene | 20.92 | C15H24 | 28624-23-9 | 71.98 | 1405 | 0.11 |
37 | 4-(Dimethylamine)-benzaldehyde | 21.02 | C9H11NO | 100-10-7 | 90.17 | 1409 | 0.90 |
38 | (E)-1-(2, 3, 6-trimethylphenyl) buta-1, 3-diene (TPB,1) | 21.29 | C13H16 | 1000357-25-7 | 58.90 | 1419 | 0.23 |
39 | β-Caryophyllene | 21.44 | C15H24 | 87-44-5 | 98.21 | 1424 | 22.68 |
40 | (+)-epi-Bicyclosesquiphellandrene | 21.67 | C15H24 | 54274-73-6 | 93.89 | 1435 | 0.75 |
41 | [1aR-(1aα, 7aα, 7bα)]-1a, 2, 3, 5, 6, 7, 7a, 7b-Octahydro-1, 1, 7, 7a-tetramethyl-1H-cyclopropa [a] naphthalene | 21.76 | C15H24 | 17334-55-3 | 82.99 | 1439 | 0.32 |
42 | (1S-cis)-1, 2, 3, 5, 6, 8a-Hexaahydro-4, 7-dimethyl-1-(1-methylethyl)-naphthalene | 21.84 | C15H24 | 483-76-1 | 75.42 | 1442 | 0.12 |
43 | α-Guaiene | 21.91 | C15H24 | 3691-12-1 | 90.65 | 1444 | 0.58 |
44 | cis-Calamenene | 22.23 | C15H22 | 72937-55-4 | 69.79 | 1457 | 0.18 |
45 | α-Humulene | 22.31 | C15H24 | 6753-98-6 | 97.41 | 1460 | 11.23 |
46 | Bicyclosesquiphellandrene | 22.54 | C15H24 | 54324-03-7 | 91.10 | 1469 | 0.61 |
47 | 2, 6-Bis (1, 1-dimethylethyl)-2, 5-cyclohexadiene-1, 4-dione | 22.61 | C14H20O2 | 719-22-2 | 91.04 | 1472 | 0.11 |
48 | cis-Muurola-4(15), 5-diene | 22.70 | C15H24 | 157477-72-0 | 68.22 | 1476 | 0.14 |
49 | (1α, 4aβ, 8aα)- (+/-)-1, 2, 4a, 5, 8, 8a-Hexahydro-4, 7-1-(1-methylethyl)-naphthalene | 22.86 | C15H24 | 5951-61-1 | 89.26 | 1482 | 0.75 |
50 | β-Guaiene | 23.00 | C15H24 | 88-84-6 | 93.97 | 1487 | 4.09 |
51 | [4aR-(4aα, 7α, 8aβ)]-Decahydro-4a-methyl-1-methylene-7-(1-methylethenyl)-naphthalene | 23.13 | C15H24 | 17066-67-0 | 87.43 | 1493 | 2.13 |
52 | 2-Isopropenyl-4a, 8-dimethyl-1, 2, 3, 4, 4a, 5, 6, 8a-octahydronaphthalene | 23.35 | C15H24 | 1000193-57-0 | 90.13 | 1501 | 2.78 |
53 | [1S-(1α, 7α, 8aβ)]-1, 2, 3, 5, 6, 7, 8,8a-octahydro-1,4-dimethyl-7-(1-methylethenyl)-azulene | 23.60 | C15H24 | 3691-11-0 | 89.20 | 1512 | 0.70 |
54 | Di-tert-butylphenol | 23.69 | C14H22O | 96-76-4 | 93.23 | 1515 | 20.11 |
55 | 1, 2, 3, 4, 4a, 5, 6, 8a-Octahydro-7-methyl-4-methylene-naphthalene | 23.80 | C15H24 | 39029-41-9 | 76.36 | 1520 | 0.37 |
56 | Selina-3, 7(11)-diene | 23.90 | C15H24 | 6813-21-4 | 54.29 | 1525 | 0.12 |
57 | (1S-cis)-1, 2, 3, 5, 6, 8a-Hexahydro-4, 7-dimethyl-1-(1-methylethyl)-naphthalene | 24.02 | C15H24 | 483-76-1 | 90.16 | 1530 | 0.90 |
58 | Epizonarene | 24.37 | C15H24 | 41702-63-0 | 63.48 | 1544 | 0.16 |
59 | Caryophyllene oxide | 24.74 | C15H24O | 1139-30-6 | 59.71 | 1560 | 0.18 |
60 | Patchoulene | 24.84 | C15H26 | 25491-20-7 | 85.19 | 1565 | 0.34 |
61 | Dehydro-aromadendrene | 25.32 | C15H22 | 85.63 | 1585 | 0.78 | |
62 | β-Vatirenene | 25.41 | C15H22 | 27840-40-0 | 72.71 | 1588 | 0.35 |
63 | Aristol-1(10)-en-9-ol | 25.47 | C15H24O | 1372763-27-3 | 81.55 | 1591 | 0.54 |
64 | (8R, 8aS)-8, 8a-Dimethyl-2-(propan-2-ylidene)-1, 2, 3, 7, 8, 8a-hexahydronaphthalene | 25.57 | C15H22 | 27840-40-0 | 69.23 | 1595 | 0.15 |
65 | Salvial-4(14)-en-1-one | 25.73 | C15H24O | 73809-82-2 | 66.55 | 1602 | 0.31 |
66 | 1, 3-Bis-(2-cyclopropyl,2-methylcyclopropyl)-but-2-en-1-one | 25.85 | C18H26O | 72.68 | 1607 | 0.11 | |
67 | [3R-(3α, 3aβ, 7β, 8aα)]-2, 3, 4, 7, 8, 8a-Hexahydro-3, 6, 8, 8-tetramethyl-1H-3a, 7-methanoazulene | 25.90 | C15H24 | 469-61-4 | 74.34 | 1610 | 0.19 |
68 | (+)-Epi-, β-santalyl acetate | 26.09 | C17H26O2 | 41414-75-9 | 75.95 | 1617 | 0.64 |
69 | (1S, 7S, 8aR)-1, 8a-Dimethyl-7-(prop-1-en-2-yl)-1, 2, 3, 7, 8, 8a-hexahydronaphthalene | 26.60 | C15H22 | 190327-38-9 | 61.30 | 1640 | 0.11 |
70 | 4a, 5-Dimethyl-3-(prop-1-en-2-yl)-1, 2, 3, 4, 4a, 5, 6, 7-octahydronaphthalen-1-ol | 26.69 | C15H24O | 61847-19-6 | 67.23 | 1645 | 0.19 |
71 | 1-Isopropyl-4, 7-dimethyl-1, 2, 3, 4, 5, 6-hexahydronaphthalene | 26.89 | C15H24 | 16729-00-3 | 59.31 | 1649 | 0.12 |
72 | (4aR-trans)-Decahydro-4a-methyl-1-methylene-7-(1-methylethylidene)-naphthalene | 27.09 | C15H24 | 515-17-3 | 80.30 | 1662 | 0.62 |
73 | trans-Valerenyl acetate | 27.14 | C17H26O2 | 101527-74-6 | 72.98 | 1665 | 0.21 |
74 | (E)-2-((8R, 8aS)-8, 8a-Dimethyl-3, 4, 6, 7, 8, 8a-hexahydronaphthalen-2 (1H)-ylidene) propyl formate | 27.41 | C16H24O2 | 352457-47-7 | 54.29 | 1679 | 0.72 |
75 | cis-α-Copaene-8-ol | 27.79 | C15H24O | 58569-25-8 | 55.35 | 1694 | 0.29 |
76 | Heptadecane | 27.98 | C17H36 | 629-78-7 | 68.57 | 1702 | 0.19 |
77 | (E)-1, 3, 3-trimethyl-2-(3-methyl-2-methylene-3-butenylidene)-cyclohexanol | 28.27 | C15H24O | 69296-93-1 | 50.18 | 1716 | 0.14 |
* The relative peak area normalization content obtained from the TIC chromatogram.