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. 2019 Jun 21;8(6):189. doi: 10.3390/antiox8060189

Table 2.

Retention time (RT), mass spectrum (MS), and polyphenolic composition (mg/g of extract) of pHWE.

RT Compound λmax MS (m/z) MS2 (m/z) Extract
pHWE
1 12.3 Quercetin-3-O-rutinoside a 254, 353 609 463, 301 3.27 ± 0.06
2 12.6 Quercetin-3-O-galactoside b 256, 354 463 301 31.37 ± 0.32
3 12.7 Quercetin-3-O-glucoside a 256, 353 463 301 8.45 ± 0.10
4 13.2 Quercetin-3-O-xylanoside b 256, 354 433 301 8.88 ± 0.10
5 13.4 Quercetin 3-O-arabinopyranoside b 243, 352 433 301 2.31 ± 0.04
6 13.5 Quercetin 3-O-arabinofuranoside b 256, 352 433 301 15.09 ± 0.16
7 13.7 Quercetin-O-pentoside b 256, 351 433 301 3.32 ± 0.05
8 13.8 Quercetin-3-O-rhamnoside b 256, 350 447 301 26.05 ± 0.27
9 14.9 Phloretin-2-O-glucoside a 227, 284 435 273 15.96 ± 0.20
Total 114.75 ± 1.25

Identification was performed based on (a) the corresponding standard; (b) UV and MSn spectra, plus elution order previously described in the literature [5,37].