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. 2019 May 21;20(13):1664–1671. doi: 10.1002/cbic.201900046

Scheme 2.

Scheme 2

A) Representative polymers with rings incorporated into their backbones.11⋅B) Chemoenzymatic synthesis of (−)‐α‐pinene‐derived lactone 10 and polyester 11 harboring a cyclobutane unit. The focus of this work is shown in the box. BVMO: Baeyer–Villiger monooxygenase, GDH: glucose dehydrogenase. For clarity, only the most substituted (i.e., normal) lactone 10 is shown and substrates for cofactor regeneration by GDH are omitted.