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. Author manuscript; available in PMC: 2019 Jul 10.
Published in final edited form as: J Am Chem Soc. 2018 Aug 7;140(32):10126–10130. doi: 10.1021/jacs.8b06069

Table 1.

Effect of Acceptor on Selectivity for Oxidative Dehydroxymethylationa

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a

Conditions: 1a (0.2 mmol), [Rh(cod)OMe]2 (2 mol%), 3-OMeBzOH (4 mol%), Xantphos (4 mol%) and acceptor (3 equiv.) in toluene (0.4 mL), 90 °C, 24 h. Yields were determined by GC using durene as an internal standard. b92% yield of CO by GC-TCD.