Table 2.
Dissociation constant of pentachlorophenol in aqueous solution at 25 °C
| Phenol concentration 1.69 × 10 −5M, cell length 10 cm, wavelength 320 mμ., D1, 0.015, D2, 0.823 | |||||
|---|---|---|---|---|---|
| I | P(α h γ ci) | D | pK | pK (corr) | |
| 0.040 | 4.851 | 0.435 | 0.034 | 4.817 | 4.816 |
| .064 | 4.838 | .426 | .015 | 4.823 | 4.822 |
| .096 | 4.827 | .422 | .006 | 4.821 | 4.821 |
| .144 | 4.814 | .415 | −.009 | 4.823 | 4.823 |
| .200 | 4.802 | .411 | −.017 | 4.819 | 4.819 |
The buffer solution contained sodium hydrogen succinate (m) and sodium chloride (m). I = 2m.