Relationship between oxyhemoglobin saturation, arterial partial pressure of oxygen (PaO2), and arterial oxygen content (CaO2). Oxyhemoglobin saturation measured by pulse oximeter (SpO2) has an accuracy of 3% when compared with the true arterial oxyhemoglobin saturation (SaO2) by co-oximetry (1 standard deviation (SD) = 3%; rectangular area represents 1 SD, and thus 68% of values; triangular areas represent 2 SD, so 95% of values). An SpO2 value of 95% can therefore represent an SaO2 between 92% and 98%. This represents a wide range in PaO2, and since adult hemoglobin (Hgb A) has a lower affinity for oxygen, for any given SaO2, the PaO2 is higher in blood containing Hgb A. Note the impact of hemoglobin on oxygen content (CaO2).