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. 2019 Jun 25;24(12):2344. doi: 10.3390/molecules24122344

Table 1.

Chemical constituents of KWM-EO determined by GC×GC-TOF MS.

Chemical Compound CAS no.a RT1b RT2c KIexpd KILite Relative Percentage (%)
1 α-Pinene 7785-70-8 6.27 0.0245 936 929 10.49
2 β-Pinene 127-91-3 7.00 0.0250 981 973 15.41
3 β-Myrcene 123-35-3 7.20 0.0243 992 993 4.86
4 β-Cymene 535-77-3 7.73 0.0253 1027 1031 3.07
5 Eucalyptol 470-82-6 7.93 0.0258 1040 1041 12.87
6 β-Ocimene 3338-55-4 8.07 0.0245 1049 1036 22.18
7 Linalool 78-70-6 8.87 0.0262 1097 1101 0.25
8 Menthone 89-80-5 9.80 0.0325 1160 1154 0.04
9 Menthofuran 494-90-6 9.93 0.0267 1169 1169 0.04
10 Levomenthol 2216-51-5 10.07 0.0277 1178 1172 0.05
11 p-Menth-8-en-2-one 5948-4-9 10.60 0.0330 1213 1218 0.07
12 Carveol 1197-07-5 10.73 0.0272 1222 1223 0.13
13 Carvone 6485-40-1 11.13 0.0327 1251 1249 1.59
14 Linalyl acetate 115-95-7 11.20 0.0270 1256 1257 0.08
15 Dihydroedulan I 63335-66-0 11.87 0.0258 1302 1292 0.28
16 β-Bourbonene 5208-59-3 13.13 0.0250 1396 1386 0.78
17 Caryophyllene 87-44-5 13.60 0.0258 1434 1431 2.80
18 Humulene 6753-98-6 14.00 0.0318 1466 1465 0.29
19 Ethyl 4-ethoxybenzoate 23676-09-7 14.73 0.0302 1524 1521 2.37
20 Viridiflorol 552-02-3 15.73 0.0272 1608 1603 3.47
Monoterpene hydrocarbons identified 56.01
Oxygenated monoterpene identified 15.86
Sesquiterpene hydrocarbon identified 3.87
Oxygenated sesquiterpene identified 3.47
Other 2.56
Identified components 81.86

a Chemical abstracts service registry number; b Retention time of the first column; c Retention time of the second column; d KIexp = Kovats indices, retention indices relative to C7–C30 n-alkanes based on the retention time of components separated by the 1st dimension Rtx-5MS column; e KILit: Retention indices reported in the literature.