Table 5.
Ref., Year |
Sorbent | Type of Water | Type of System | REEs (III) | [REEs]0 (µg/L) |
pH | T (°C) | Time of Contact (h) | m(Sorbent)/ V(Solution) (mg/L) |
qm (mg/g) or REEs Adsorption (%) |
---|---|---|---|---|---|---|---|---|---|---|
[94], 2017 |
GO colloid | Ultrapure | Multi elements | La, Nd, Gd, Y | 5 × 103 | 6 | r.t. | 0.5 | 10 × 102 | La = 85.7 mg/g Nd = 189 mg/g Gd = 226 mg/g Y = 136 mg/g |
[95], 2017 |
GO colloid | Ultrapure | Multi elements | La, Nd, Gd, Y | (5–50) 103 |
3-8 | 5–45 | 0.02–2 | 10 × 102 | |
[91], 2015 |
GO | Ultrapure | Mono element | Eu | 10 × 103 NaClO4 = 0.01 mol/L |
4.5, 7 |
20 | 0–24 | 10 × 102 | 90%, 89.7 mg/g |
[92], 2015 |
MGO | Ultrapure | Mono element | Eu | 10 × 103 NaClO4 = 0.01 mol/L |
4.5, 7 |
20 | 0–24 | 10 × 102 | 80%, 70.2 mg/g |
[92], 2015 |
GO e MGO | Ultrapure | Mono element | Eu | (1–50) ×103 |
2–11 | 20, 40, 60 | 0–24 | 10 × 102 | |
[101], 2012 |
GONS | Ultrapure | Mono element | Eu (1) | 51 × 103 NaClO4 = 0.01 mol/L |
2 4.5 6 7 |
25 | 48 | 2 × 102 | 65%, 167.16 mg/g 161.29 mg/g 175.44 mg/g 100% |
[101], 2012 |
GONS | Ultrapure | Mono element | Eu | 51 × 103 NaClO4 = 0.01 mol/L |
2–11 | 25, 45, 65 | 48 | 2 × 102 | |
[100], 2016 |
GO | Ultrapure | Mono element | Eu | 10 × 103 NaCl = 0.1, 0.01, 0.001 mol/L |
5.5 | 20 | 0–24 | 5 × 102 | 100%, 143 mg/g |
[100], 2016 |
GO-OSO3H | Ultrapure | Mono element | Eu | 10 × 103 NaCl = 0.1, 0.01, 0.001 mol/L |
5.5 | 20 | 0–24 | 5 × 102 | 90%, 125 mg/g |
[100], 2016 |
GO e GO-OSO3H | Ultrapure | Mono element | Eu | 10 × 103 NaCl = 0.1, 0.01, 0.001 mol/L |
1–11 | 20 | 0–24 | 5 × 102 | |
[92], 2014 |
GO colloid | Ultrapure | Mono element | Gd | 12 × 103 | 5.9 (2–11) |
30 | 0.5 | 0.4 × 102 | 287 mg/g |
[93], 2014 |
GO colloid | Ultrapure | Mono element | Y | 12 × 103 | 5.9 | 30, 40 | 0.42 | 0.4 × 102 | 190 mg/g |
[99], 2016 |
GO | Ultrapure | Mono element | Eu | 0.01 × 103 NaCl = 0.01M |
5.0, 2.7–7.3 |
r.t. | 48 | 1 × 102 | 78.0 mg/g, 97% |
[99], 2016 |
GO | Ultrapure | Mono element | Eu | (0.01–100) × 103 | 1–8 2,4,6 |
r.t. | 48 | 1 × 102 | |
[98], 2017 |
GO | Ultrapure | Mono element | Sc | 300 × 103 | 2 4 |
r.t. | 4 | 50 × 102 | ~ 95%, 36.5 mg/g 39.7 mg/g |
[98], 2017 |
GO | Ultrapure | Mono element | Sc | (1–300) × 103 | 1–5.5 | r.t. | 0.02–0.5 | 50 × 102 | |
[96], 2017 |
30%Mo4W8@EDMG, 30%Mo2W10@EDMG |
Ultrapure | Mono element | Ce | 10 × 103 | 6 (2–6) |
20 | 0.08–3 | 17 × 102 | 90.9 mg/g, 96.2 mg/g |
[95], 2014 |
MPANI-GO | Ultrapure | Multi elements | Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu | 0.01 × 103 | 4 | r.t. | 0.33 | 4 × 102 | Y = 8.10, La = 15.5, Ce = 8.60, Pr = 11.1, Nd = 8.50, Sm = 7.70, Eu = 11.0, Gd = 16.3, Tb = 11.8, Dy = 16.0, Ho = 8.10, Er = 15.2, Tm = 10.4, Yb = 10.3, Lu = 14.9 mg/g |
[96], 2014 |
MPANI-GO | Ultrapure | Multi elements | Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu | (0.00025, 0.0005, 0.001, 0.002, 0.01) × 103 |
2–9 | r.t. | 0.02–0.25, 0.33 | (0.25–20) × 102 | |
[90], 2013 |
PANI@GO | HClO4 (aq) 0.01 mol/L | Mono element | Eu | 15 × 103 | 3 | 25 | 48 | 2.5 × 102 | 251 mg/g |
[97], 2017 |
TGA/CdTeQDs/Fe3O4/rGONS | Distilled | Mono element | Ce | 0.05 × 103 (1–100) × 103 |
5.0 | 35 | 0.17 | 7 × 102 | 95% 56.8 mg/g |
[102], 2017 |
TGA/CdTeQDs/Fe3O4/rGONS | Distilled | Mono element | Ce | (1–100) × 103 | 2-8 | 35 | 0.02–0.25 | (2–9) × 102 | |
[102], 2014 |
GTiP-1 | Ultrapure | Mono element | Eu | 100 × 103 | 1 3.7 5.5 7.3 |
25 | 2 | 10 × 102 | ~ 3.0% ~ 32% 35% ~ 72% |
[103], 2014 |
GTiP-2 | Ultrapure | Mono element | Eu | 100 × 103 | 1 3.7 5.5 7.3 |
25 | 2 | 10 × 102 | ~ 10% ~ 45% 50% ~ 80% |
[103], 2014 |
GO | Ultrapure | Mono element | Eu | 100 × 103 | 1 3.7 5.5 7.3 |
25 | 2 | 10 × 102 | ~ 7.0% ~ 20% 20% ~ 28% |
[103], 2014 |
GO, GTiP-1, GTiP-2 | Ultrapure | Mono element | Eu | (5–200) × 103 Na+ = 1, 10, 100, 1000 mM |
1.7, 3.7, 5.5, 7.3 | 25 | 2, 4 | 10,000 × 102 |
(1) Adsorptions experiments were conducted under N2 conditions. r.t. means room temperature. The ultrapure water was provided by Milli-Q system. Note that the optimal experimental conditions are represented by shading and the other conditions tested and described in the papers are represented on a white background (without shading).