Table 7.
Upgrading Techniques | Process Conditions | Pros. | Cons. |
---|---|---|---|
Extraction | Mild conditions, solvents | Extracts valuable chemicals from bio-oil | Low cost separation and refining techniques are still needed |
Solvent addition | Mild conditions, polar solvents | Simple | No chemical reaction to convert or remove undesired compound within bio-oil |
Emulsification | Mild conditions, surfactant | Simple | High energy consumption, no chemical reaction to convert or remove undesired |
Esterification/alcoholysis | Mild conditions, alcohol | Relatively simple, mild conditions, low cost of alcohol if methanol is used | Not effective to remove nitrogen-containing compounds |
Supercritical fluids (SCFs) | Relatively high pressure and temperature, organic solvents | Effective to increase HHV and reduce viscosity | Needs high pressure equipment, some solvents are expensive |
Hydrotreating | Relatively high pressure and temperature, catalysts | Removes N, O, and S as NH3, H2O, and H2S, and increase HHV, commercialized already | Needs high pressure equipment, high cocking and catalyst deactivation |
Catalytic cracking | Relatively high temperature, atmospheric pressure, catalysts, | Produces large amounts of light products | Needs high pressure equipment, catalyst deactivation |
Steam reforming | High temperature, catalyst | Produces H2 as a clean energy resource | Needs high temperature equipment |