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. 2019 Jun 17;24(12):2250. doi: 10.3390/molecules24122250

Table 7.

Brief description of bio-oil upgrading techniques.

Upgrading Techniques Process Conditions Pros. Cons.
Extraction Mild conditions, solvents Extracts valuable chemicals from bio-oil Low cost separation and refining techniques are still needed
Solvent addition Mild conditions, polar solvents Simple No chemical reaction to convert or remove
undesired compound within bio-oil
Emulsification Mild conditions, surfactant Simple High energy consumption, no chemical reaction to convert or remove undesired
Esterification/alcoholysis Mild conditions, alcohol Relatively simple, mild conditions, low cost of alcohol if methanol is used Not effective to remove nitrogen-containing
compounds
Supercritical fluids (SCFs) Relatively high pressure and temperature, organic solvents Effective to increase HHV and reduce viscosity Needs high pressure equipment, some solvents are expensive
Hydrotreating Relatively high pressure and temperature, catalysts Removes N, O, and S as NH3, H2O, and H2S, and increase HHV, commercialized already Needs high pressure equipment, high cocking and catalyst deactivation
Catalytic cracking Relatively high temperature, atmospheric pressure, catalysts, Produces large amounts of light products Needs high pressure equipment, catalyst
deactivation
Steam reforming High temperature, catalyst Produces H2 as a clean energy resource Needs high temperature equipment