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. 2019 Jul 18;9:10416. doi: 10.1038/s41598-019-46796-3

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© The Author(s) 2019

Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.

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(a) Merged XANES spectra recorded in the leaves of P. vulgaris plants exposed to 10 mg Zn L⁻¹ of ZnSO_4(aq), 40 nm ZnO and 300 nm ZnO for seven days, and reference compounds used in the linear combination analysis; (b) merged XANES spectra data and linear combination fitting. Regardless the source of Zn supplied to roots, Zn was mainly stored in a chemical form similar to Zn₃(PO₄)₂ combined to minor fractions of Zn-histidine like compound.