| A, B, C, r |
constants for eq (5.1). |
|
Ai
|
coefficients for liquid density formula. |
|
Bi
|
coefficients for rectilinear diameter formula. |
|
Ci
|
coefficients of formula for Cb.
|
|
Di, Ei
|
binomial coefficients (appendix IV). |
|
Ca
|
gross heat capacity adjusted for curvature. |
|
Cb
|
heat capacity of empty calorimeter bomb. |
|
specific heat, two-phase sample, adjusted for curvature. |
|
specific heat of two-phase sample at constant total volume. |
| Cσ |
specific heat of liquid on coexistence path. |
| E |
internal energy. |
|
Eb
|
volt-box output potential. |
|
Es
|
potential across standard resistor for heater current. |
| H |
enthalpy. |
| ΔHV
|
heat of vaporization. |
| J |
the joule. |
| k |
conversion factor, 0.101325 J/cm3 atm. |
| N |
total g moles of fluid in bomb plus capillary tube. |
|
Nb
|
g moles of fluid in the bomb. |
|
Nc
|
g moles of fluid in the capillary tube. |
| P |
pressure, 1 atm = 0.101325 MN/m2. |
| Q |
heat energy; also calorimetric heat input. |
|
Q/ΔT
|
unadjusted, gross heat capacity. |
|
Rb
|
volt-box input resistance. |
|
Rl
|
input Jead-wire resistance. |
| ρ |
density. |
| S |
entropy. |
| t |
time. |
| T |
temperature, Kelvin. |
|
T1, T2
|
initial and final temperatures of a heating interval. |
|
Ta
|
average temperature in ΔT
|
|
Tc
|
critical-point temperature, 154.77 K. [17] |
|
Tt
|
triple-point temperature, 54.3507 K. [17, 18] |
| ΔT
|
calorimetric temperature increment, deg. Celsius. |
| υ |
molal volume, 1/ρ. |
|
Vb
|
volume of the calorimeter bomb. |
|
Vl
|
total liquid volume. |