Table 3. Dissociation temperatures of Ln2O3 · PdO compounds.
All radii of the rare earth cations taken from Arhens [16] with the exception of Y+3 which was taken from Roth and Schneider [8]. Parenthesis indicate decomposition temperatures of metastable 1:1 compounds.
| SYSTEM | RADIUS OF Ln+3 Å |
DISSOCIATION TEMP. °C | ||
|---|---|---|---|---|
| 2 Ln2O3 · PdO | Ln2O3 · PdO | Ln2O3 · 2 PdO | ||
| La2O3 - PdO | 1.14 | 1190 | — | 1105 |
| Nd2O3 - PdO | 1.04 | 1135 | (860) | 1085 |
| Sm2O3 - PdO | 1.00 | 1115 | (940) | 1060 |
| Eu2O3 - PdO | 0.98 | 1085 | (985) | 1045 |
| Gd2O3 - PdO | 0.97 | — | (1005) | 1025 |
| Dy2O3 - PdO | 0.92 | — | (1030) | — |
| Ho2O3 - PdO | 0.91 | — | — | — |
| Y2O3 - PdO | 0.91 | — | — | — |
| Er2 O3 - PdO | 0.89 | — | — | — |
| Tm2O3 - PdO | 0.87 | — | — | — |
| Yb2O3 - PdO | 0.86 | — | — | — |
| Lu2O3 - PdO | 0.85 | — | — | — |