Skip to main content
. 1968 Jan-Feb;72A(1):27–37. doi: 10.6028/jres.072A.004

Table 3. Dissociation temperatures of Ln2O3 · PdO compounds.

All radii of the rare earth cations taken from Arhens [16] with the exception of Y+3 which was taken from Roth and Schneider [8]. Parenthesis indicate decomposition temperatures of metastable 1:1 compounds.

SYSTEM RADIUS OF Ln+3 Å
DISSOCIATION TEMP. °C
2 Ln2O3 · PdO Ln2O3 · PdO Ln2O3 · 2 PdO
La2O3 - PdO 1.14 1190 1105
Nd2O3 - PdO 1.04 1135 (860) 1085
Sm2O3 - PdO 1.00 1115 (940) 1060
Eu2O3 - PdO 0.98 1085 (985) 1045
Gd2O3 - PdO 0.97 (1005) 1025
Dy2O3 - PdO 0.92 (1030)
Ho2O3 - PdO 0.91
Y2O3 - PdO 0.91
Er2 O3 - PdO 0.89
Tm2O3 - PdO 0.87
Yb2O3 - PdO 0.86
Lu2O3 - PdO 0.85